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Rechargeable
Batteries — compared and explained in detail
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The
higher the capacity, the worse the shelf life |
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Type of NiMH |
Largest capacity |
Capacity after 1 year idle |
Number
of charge cycles |
Price
for 4 AA |
Normal NiMH |
2700 mAh |
0% |
300-800 |
$8.99 |
eneloop pro (LSD) |
2500 mAh |
85% |
500 |
$19.95 |
eneloop (LSD) |
2100 mAh |
85% |
2100 |
$9.49 |
Self-Discharge. Normal NiMH's have the highest self-discharge rate of any kind of battery (meaning they lose charge just by sitting around, unused), but there are Low Self-Discharge (LSD) versions available (like eneloop). The tradeoff is that the LSD versions have a little lower capacity. So when buying NiMH's, you have to choose between longer shelf life or higher capacity. If you burn through batteries quickly, get the regular NiMH's so you can enjoy the larger capacity. But if you go months before using up the battery's capacity, go for LSD instead. The table at right shows the relationship between self-discharge and capacity.
One nice thing about the LSD versions is that they come pre-charged. Regular NiMH's must be charged before use.
Voltage. NiMH's are rated at 1.2V initial voltage,
which is lower than the 1.5V that alkalines put out at
first. This is generally not a problem, but it does mean
that flashlights will be dimmer at first, and devices that need
4 or more batteries might burn through the batteries very
quickly or not work at all. On the other hand, some
devices (like many digital cameras) are designed to work
with the lower 1.2V, so the reduced voltage is definitely not a
problem there. If NiMH's don't supply enough voltage for
your device, consider NiZn's,
or mixing NiMH and NiZn together, after seeing the caution about
mixing NiMH and NiZn in the same
device.
Voltage Drop. Like most other rechargeables, NiMH batteries maintain most of their voltage over the whole charge and then suddenly plummet. This contrasts to alkalines, which lose their capacity steadily. For this reason many electronic devices that tell you how much battery life is left have a hard time reporting an accurate level for NiMH's. The voltage is very similar for both a fully-charged battery and a nearly-spent battery. Some devices (like my GPS wristwatch) let you specify in the setup menu whether you're using NiMH or alkalines, so they can try to be more accurate with the battery-remaining indicator.
Charging. Overcharging can reduce cycle life (the number of times the battery can be charged). Smart chargers know when the battery is full and stop charging. Dumb chargers run on a timer and will almost always overcharge or fail to fill up the battery completely, and they usually really fail to fill up C and D sizes. Charging NiMH with old NiCd chargers is not recommended. (Modern chargers handle both NiMH's & NiCd's.) Note that some smart chargers are better than others, too.
I haven't been able to find out whether you get more cycles but charging NiMH's early vs. waiting until they're deplated, but it probably doesn't matter: You can typically charge NiMH's hundreds of times without special care, so I wouldn't worry about it, and suggest you just charge whenever you like.
An ideal charge rate is probably around 4-6 hours (for empty to full). Faster than that will work, but isn't optimal. For slower charges, besides wasting time, there's the possibility that a smart charger will miss the cutoff signal that tells it to stop charging.
Energizer recommends storing NiMH batteries
in a charged state, and to exercise them (alternatively drain
and charge) a few times to restore their capacity. (PDF,
#20) Some chargers I
recommend will exercise the batteries for you
automatically.
See the Charging Tips page for more about charging.
Cycle Life. NiMH's are good for hundreds of charge cycles in theory, but overcharging and repeatedly running the batteries down all the way can reduce cycle life. To avoid overcharging, use a smart charger that stops charging when the battery's had enough. (See the chargers page for recommendations.) You'll also get more cycles if you charge your batteries before they're fully run down.
The original (2005) Sanyo Eneloop
LSD's were rated for 1000 cycles, and the newest ones are rated
for 1500 and 1800 cycles, though it would take years and years
for most users to get to even 1000 cycles.
Recycling. When your battery no longer holds a charge or its capacity is no longer useful, you can easily recycle it at over 30,000 locations in U.S. & Canada such as Sears, Office Depot, Home Depot, Target, Wal-Mart, Best Buy, and others. Find the nearest location to you from Call2Recycle.
Memory Effect. While NiMH batteries supposedly don't suffer from the memory effect that NiCd batteries supposedly did, NiMH batteries do sometimes suddenly deliver much reduced capacity each cycle. This can be easily fixed by a good charger that has a "Refresh" setting. (It drains the battery completely and then gives it a full charge, sometimes repeating the process a few times or until capacity no longer improves.)
Pros:
Reliability. PowerGenix NiZn's suffer from
reliability problems. See below for my poor experience
with capacity. Also, NLee
reports that after buying four cells and putting them through
20-30 deep cycles (0.9V), two failed (reduced voltage and rapid
self-discharging), and the other two suffer from reduced
capacity (80% of original). Many customers on Amazon
report their batteries dying prematurely too. It appears
that over-discharging NiZn's can easily damage them.
(NiMH's are more tolerant of an over-discharge.)
High-Drain Performance. High-drain devices are those which need lots of power quickly, like digital cameras. That's as opposed to devices that just sip the juice slowly, like clocks. NiZn work great in high-drain devices, if the voltage isn't an issue. (See the Voltage section below.)
Capacity and Run Time. There are many reports of
reliability problems, including my own experience, which kind of
make any published specs about capacity moot. I used 9 for
about a year (probably fewer than 10 cycles) in electric
toothbrushes and electronic door locks. Seven of the nine
(Star Trek Voyager reference unintentional) dropped to only
45-150mAh in capacity, and the remaining two were 996 and
1298mAh. They should have been 2500mWh ÷ 1.65V =
1515mAh. NLee
the Engineer says that after just a year, 2 of the 4 he
purchased suffered reduced capacity down to 80% of the original,
and the other 2 simply failed. Many others have made
similar complaints. The following discussion assumes that
NiZn's don't suffer reduced capacity early, although that's
probably not the case.
NiZn's give either longer, shorter, or
fairly equal run time vs. other kinds of batteries, depending on
what device you use them in. engadget
said that they got 300-400 flashes from their camera flash unit
with NiZn's, vs. only 200-300 with NiMH's, and Tom's
Guide said their NiZn's ran a CD player for three times
longer than NiMH's. However, devices which don't limit the
input voltage (like most flashlights and electric toothbrushes,
for example) will run out faster with NiZn's, because while the
device was running the light was burning brighter or the motor
was spinning faster. NiZn's will make camera flashes
recycle much faster, though burning through lots of flash shots
quickly can fry the flash. Also, the NiZn might not give
as many usable flashes as NiMH, since NiZn's may
start off with super-fast flash recycle times, but then get
slower than NiMH. (Strobist
quotes a user that said NiZn's got worse than NiMH after 50-75
shots, and too slow to use after 200 shots, compared to 400
shots for NiMH.)
PowerGenix quoted capacity for
AA and AAA was 1500 and 700 mAh respectively. That's about
half of the best NiMH's. PowerGenix therefore listed the
spec on its battery in mWh (total energy) rather than mAh,
because total energy between battery types is more similar, and
PowerGenix says that's a more apples-to-apples comparison.
That's debatable, from either side. It's true that the
total energy is the same, but again, if the device being used
doesn't limit the voltage, the device will use the extra voltage
and the NiZn will spend its energy faster, so the NiZn's will
provide less runtime. (And if the device does
limit the voltage, then there's no advantage to using NiZn's in
the first place, because the only reason you'd use them instead
of NiMH's is if you needed the extra voltage to begin with.)
Voltage. NiZn's have the highest initial voltage of any rechargeable AA or AAA battery. The nominal voltage is 1.65, and fresh out of the charger the voltage is as high as 1.85V. (PowerGenix, PDF, and my tests) This is way higher than the 1.5V for alkalines. The higher voltage can be both a blessing and a curse. The upside is that flashlights burn brighter, and battery life will generally be longer in high-drain devices. (Some LED lights limit the voltage, so in that case NiZn's won't be brighter than 1.5 alkalines, but they'll still be brighter than 1.2V NiMH's.)
But there are downsides to the extra voltage. For lights, the brighter light means that the bulbs will burn out faster, sometimes immediately. (Tom's Guide) For cameras, a rapid flash cycle can fry the flash. (Amazon review) For electronics, first understand that some devices have a voltage regulator (which limits the max voltage coming from the batteries) or a voltage protector (which shuts off the device if the battery input is too high). If your device doesn't have one of these, and the device is very sensitive to voltage, then the batteries might fry it. It's hard to know whether a particular device is a "fry", "auto shut-off", or "no problem" variety. (Good luck.) The fewer batteries your device takes, the less likely you are to have a problem. A one-batery device is the least dangerous, two-batteries are a little more so, four batteries even more, and with 8+ batteries you're just asking for trouble. Powergenix mostly ignores this problem in their marketing materials, so shame on them.
If you're worried that NiZn's could be too hot for your device, then NiMH would be a better bet. If NiMH doesn't supply enough voltage for your device, you can mix NiMH and NiZn together, after seeing the caution about mixing NiMH and NiZn in the same device.
Self-Discharge. Powergenix claims a self-discharge rate of 8% per month, but NLee the Engineer's tests showed 13% per month, and I'm inclined to trust him. Self-discharge means the bateries lose their charge by just sitting around, unused. Unlike NiMH's, there is no low self-discharge version available. If you use up and recharge your batteries quickly this won't matter to you. But if you need longer shelf life, you'll want to consider a LSD NiMH instead.
Voltage Drop. Like most other rechargeables, NiZn batteries maintain most of their voltage over the whole charge and then suddenly plummet. This contrasts to alkalines, which lose their capacity steadily. For this reason many electronic devices that tell you how much battery life is left have a hard time reporting an accurate level for rechargeables, but this is especially true for NiZn's, because their voltage is so high.
Charging. You need a special NiZn charger for these cells. NiMH chargers will not work! (See below for those who insist trying anyway.) PowerGenix made two chargers: the white charger was smart and managed each cell separately, but had only one status LED and it didn't light up until all the batteries were done. (If one cell was bad, the red charge light would blink. Then you got to play musical batteries figuring out which one was bad.) The black charger required charging in pairs, and didn't manage the batteries separately. Never buy a charger like that.
The white charger is labeled a "1-hour charger", but what that really means is that the batteries mostly full after an hour, but not completely. Powergenix says it takes about 1.5 hours to charge 1-2 AA's, and 2.5 hours to charge 3-4 AA's. Unlike NiMH's, NiZn's tolerate fast-charging
well. The PowerGenix
spec
sheet suggests a rate of between C/2 to C is okay (30
minutes to 1 hour).
Charging NiZn's in
a NiMH charger. It's theoretically
possible to charge NiZn's with a NiMH charger, but there are at
least three problems. First, even a smart NiMH charger
probably won't know when to stop charging NiZN's, and will
overcharge, damaging the battery. Overcharging is harder
on NiZn's than NiMHs. Second, how will you know
when to stop charging? Armed with PowerGenix's recharge
profile chart (PDF) and the battery and charger specs you
could make a guess. (Good luck.) Finally, the
charging profile of a NiZn is different from a NiMH. A
NiZN should get less and less charging current as it approaches
fullness, but NiMH chargers don't do that. The
top-of-the-line La Crosse BC-series
NiMH chargers put a minimum of 200mA into the batteries, for
example, while the NiZn's should get only about 100mA near the
end of the charge. I don't know the penalty for feeding
more current than is recommended, but a shorter cycle life is my
guess. Again here's PowerGenix's
recharge profile chart (PDF). All that said, in a
pinch, I've used my La Crosse BC-700 to slightly recharge NiZn's
while traveling when I forgot to pack my NiZn charger, but I've
terminated the charge well before the cells could be
overcharged. When you put the cells in the BC charger
they'll read "FULL" if their voltage is over ~1.3 volts, so I
overrode that by pressing the cell button and then the Mode
button to switch to charging mode. I monitored the voltage
and took them out when they hit 1.8V, although you should be
safe by going up to 1.9V. Even so, at that point your
batteries will likely be only about half full. Anyway, all
this is at your own risk, of course.
Discharged Voltage. The
PowerGenix
site provides absolutely no guidance as to how far NiZn's should
be drained before charging to maximize capacity and cycle
life. (Shame on them.) The typical discharge level
for rechargeable batteries is 1.0 to 1.1V, and 1.1V is when I
try to recharge my batteries (both NiMH and NiZn). The
charger won't recognize them at <0.5V, but even though the
charger will recognize a 0.6V cell, its capacity or reliability
might be greatly reduced if you drain your cells to that level.
Problems with the charger. NLee
says that the charger stops charging when the voltage hits 1.9V,
but if the battery is damaged and can't reach 1.9V, the charger
will just keep charging and ruin the battery. That's not
my experience: I had a damaged cell that showed as full at
only 1.16V.
NLee also
says that batteries left in an unplugged charger will
drain 10-100 times faster than batteries left in other chargers,
which means that they'll be discharged after only ten days.
Pros:
Pros:
Intro. NiCads are obsolete rechargeables. They've
been replaced by Nickel-Metal Hydrides (NiMH).
NiCd's don't have any advantages over NiMH, and they have lousy
capacity and are toxic to boot. The only reason to use
NiCd's is if you already have some—though even then, if you
upgrade to a modern battery you won't have to charge them so
often. NiCds are hard to find now, but why would you want
to?
High-Drain Performance. NiCd's deliver the juice fast enough to power high-drain devices like digital cameras—but not for long, since their capacity is so weak.
Capacity. Different brands have different capacities, but with NiCd it's always low anyway (which is why you should be using NiMH instead). The AA size has 600-1000 mAh (compared to 1200-2900 for a NiMH), and the D size has 1800-5000mAh (vs. 2200-12,000 for NiMH). Note that many cheap chargers fill up the D size to only a AA capacity, giving really awful run time. (See our recomended chargers.)
Memory Effect. The theory of the NiCd memory effect is that if you repeatedly partially discharge a battery to the same level before charging it, it will "remember" the discharge level and then always fail at that point during use, never allowing the full capacity of the battery to be used. Many observers don't believe that this effect is real, and most of those who do admit that it's hard to reproduce and can be fixed by cycling with a good battery charger anyway. Now, NiCd's (and NiMH's) can suffer decreased capacity due to repeated deep-discharging or overcharging, and many people mistakenly blame the resulting reduced capacity on the memory effect. (Wikipedia, Dan's Data, Repair FAQ) But the real problem wasn't a memory effect, it was deep-discharging or overcharging. NiCd's & NiMH's with reduced capacity can often be resurrected by exercising them (discharging down to 1.0V), or conditioning them in a charger that has a refresh mode. (Battery University, & personal experience)
Self-Discharge. NiCd's discharge quickly (meaning
they lose charge just by sitting around, unused). They
typically lose 10% of their initial charge in the first month,
and then 10% of the initial charge each successive month.
Voltage. At 1.2V, no other battery has less voltage than NiCd's. (For reference, alkalines are 1.5V.) This is generally not a problem, but it does mean that flashlights will be dimmer, and devices that need 4 or more batteries might not work at all.
Voltage Drop. Like most other rechargeables, NiCd
batteries maintain most of their voltage over the whole charge
and then suddenly plummet. This contrasts to alkalines,
which lose their capacity steadily. (See the chart under NiMH.)
For
this reason many electronic devices that tell you how much
battery life is left have a hard time reporting an accurate
level for NiCd's. The voltage is very similar for both a
fully-charged battery and a nearly-spent battery.
Charging. Overcharging can reduce cycle life (the number of times the battery can be charged). Smart chargers know when the battery is full and stop charging. Dumb chargers run on a timer and will almost always overcharge or fail to fill up the battery completely, and they usually really fail to fill up C and D sizes. Note that even some smart chargers are better than others. See the chargers page for charger recommendations.
You can charge whenever you like, but
constantly draining them completely before charging shortens
their life. Occasional draining down to 1.0V is
okay, and recommended. Very slow charging can damage the
batteries. (Ken
Nishimura, an electrical
engineer with a PhD from UC Berkeley)
Cycle Life. NiCd's are good for hundreds of charge
cycles in theory, but overcharging and repeatedly running the
batteries down all the way can reduce cycle life. To avoid
overcharging, use a smart charger that stops charging when the
battery's had enough. (See the chargers
page for recommendations.) You'll also get more cycles if
you charge your batteries before they're fully run down.
Recycling. When your battery no longer holds a charge or its capacity is no longer useful, you can easily recycle it at over 30,000 locations in U.S. & Canada such as Sears, Office Depot, Home Depot, Target, Wal-Mart, Best Buy, and others. Find the nearest location to you from Call2Recycle.
9V size is especially puny. NiCds are already very
weak compared to NiMH, but the 9V size of NiCds is especially
weak. NiCd "9V" voltage is actually only 7.2V (or 8.4V if
you're lucky), while NiMH voltage is typically 9.6V or sometimes
8.4V. See more on 9V-size
rechargeable batteries.
More: Radio
Shack's technical info in NiCds
Pros:
Summary. These are often called RAMs, for
Rechargeable Alkaline Manganese. When they came out in
1992 they were competing against rechargeable NiCd's, and
claimed the best of both worlds—reusable like a NiCd, but with
the higher voltage and long shelf life of an alkaline.
Those advantages have been narrowed now that LSD
NiMH's offer long shelf life and NiZN's
offer higher voltage, but RAMs remain the only battery that
offers both long shelf life and higher voltage
in the same package. Of course, there are some
downsides:
Where to Buy. There were only a couple of
manufacturers left circa 2012, and now that I check again in
2017, it appears there are no more sources. (As for the
2012 manufacturers, Pure Energy seems to have gone out of
business, and Accucell doesn't make RAMs any more. Rayovac
discontinued its Renewal brand RAMs in 2004, and the Juice and
Lenmar brands appear to have disappeared circa 2011.)
High-Drain Performance. RAMs don't work in devices that need lots of juice quickly, like digital cameras. For high-drain devices use NiMH or NiZn.
Capacity. Initial capacity of RAMs is often
dramatically lower than a real alkaline, or even a NiMH for that
matter. Also, the capacity of a RAM decreases after every
use/recharge cycle. For example, Pure Energy brand RAMs
lose half their capacity after 25 deep-discharge cycles. (PDF)
Lenmar
are worse, becoming useless after 25 deep-discharge
cycles. Considering that the capacity drops on each
recharge cycle, a Lenmar RAM effectively provides the same
amount of energy over 25 cycles as 10 regular alkaline batteries
would have. In other words, a single Lenmar RAM replaces a
whopping 2.5 regular alkalines, and then only after you've
screwed around recharging it 25 times.
RAMs retain much more capacity and can
be recharged many more times if they're recharged before being
depleted—the sooner the better. They may be able to be
charged 100's of times that way, and will offer much more
lifetime capacity vs. deep discharging. Of course, it's a
hassle to constantly recharge your batteries when they're only
partially drained.
Self-Discharge. RAMs have the lowest
self-discharge rate of any rechargeable battery—less than 1% of
their initial charge per month. That's way less than even
the low self-discharge flavor of NiMH's. This makes RAMs
good for infrequently-used devices, or devices which take months
to use up the battery (e.g., clocks). Though I'd still
prefer LSD NiMHs, and avoid the risk of leaks.
Voltage. At 1.5V, the RAMs voltage is just about
ideal compared to other rechargeables—it's higher than the 1.2V
of NiMH's (so lights run brighter), but lower than the 1.65V of
NiZn's (so you don't risk blowing bulbs or frying
electronics). However, just like the capacity drops on
every charge, voltage can drop as well.
Voltage Drop. RAMs lose their
voltage gradually over their use like regular alkalines (not
suddenly like NiMH's and NiZN's). See the chart under NiMH
for a picture.
Charging. You need a special charger for RAMs, a
regular NiMH charger won't work. Capacity is retained (and
cycle life is greatly increased) by charging RAMs before they're
fully depleted—the sooner the better. RAMs will offer much
more lifetime capacity this way. RAMs take a lot more time
to charge than other rechargeable batteries. Here's my
page of RAM chargers.
Cycle Life. RAMs offer the fewest deep recharge
cycles of any rechargeable battery, but if you're not charging
your batteries every day RAMs could be a good fit for you.
(If you are charging your batteries every day, look at NiMH
or NiZn.) The worst
RAMs likely get at least 20 cycles. Pure Energy claims at
least 50 deep recharge cycles, thanks to a combination of
improved battery chemistry and their optimized battery
charger. For shallow discharges, recharge cycles could go
into the hundreds, and at least in Pure Energy's case, into the
thousands. (See Pure Energy's PDF
report.)
Recycling. It's a lot harder to find places to recycle RAMs than real rechargeables like NiMH and NiZN. See the Alkalines > Recycling section for more.
Why there aren't 9V rechargeable alkalines. From the Rayovac website: "There are two reasons: (1) 9V batteries actually have six small 1.5 V-cells inside them. Reusable alkalines need to be charged individually for reliable performance. Since you can't access each cell inside the 9V battery individually, they could not be reliably recharged. (2) Most products designed to run from 9-Volt batteries last for many months. Recharging these batteries provides limited benefit in terms of cost savings (the cost of replacing batteries is not significant anyway)."
More: Battery University on rechargeable alkalines.
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Michael Bluejay’s
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